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The microsomal metabolism of [7,12-3H]7,12-dimethylbenz[alpha]anthracene by the rat and hamster was examined. Microsomes from the rat and hamster catalyzed the 7,12-dimethyl-7-hydroxybenzo[alpha]anthracene (13-OH-DMBA) and the 7,12-dimethyl-7,8-dihydroxybenzo[alpha]anthracene (8-OH-DMBA) formation. Metabolites of [7,12-3H]7,12-dimethylbenz[alpha]anthracene formed in rat liver microsomes were 4-OH-DMBA, 3-OH-DMBA, 4-OH-DMBA-13-methyl ether, 4-OH-DMBA-3-methyl ether, 4-OH-DMBA-13-ethyl ether, 3-OH-DMBA-13-methyl ether, 3-OH-DMBA-3-methyl ether, 3-OH-DMBA-13-ethyl ether, 7-OH-DMBA, 7-OH-DMBA-3-methyl ether, 7-OH-DMBA-13-methyl ether, and 7-OH-DMBA-13-ethyl ether. Major metabolites of [7,12-3H]7,12-dimethylbenz[alpha]anthracene formed in hamster liver microsomes were 3-OH-DMBA, 3-OH-DMBA-13-methyl ether, 3-OH-DMBA-13-ethyl ether, 4-OH-DMBA-13-methyl ether, 3-OH-DMBA-3-methyl ether, and 4-OH-DMBA-3-methyl ether. Compound-specific metabolic profile analysis indicates that the 4-OH-DM 0b46394aab
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